Universal aging features in the restructuring of fractal colloidal gels.

نویسندگان

  • L Cipelletti
  • S Manley
  • R C Ball
  • D A Weitz
چکیده

We use multispeckle dynamic light scattering to measure the dynamic structure factor, f(q,tau), of gels formed by aggregation of colloids. Although the gel is an elastic solid, f(q,tau) nearly completely decays on long time scales, with an unusual form, f(q, tau) approximately exp{-(tau/tau(f))(mu)}, with mu approximately 1.5 and with tau(f) proportional variant q(-1). A model for restructuring of the gel with aging correctly accounts for this behavior. Aging leads to a dramatic increase in tau(f); however, all data can be scaled on a single master curve, with tau(f) asymptotically growing linearly with age. This behavior is strikingly similar to that predicted for aging in disordered glassy systems, offering convincing proof of the universality of these concepts.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Mechanical Properties of Colloidal Gels Subject to Particle Rearrangement

In a colloidal suspension with attractive interaction, particles form aggregates that settle to the bottom of the container. As the concentration of particles is increased, the overlapping of the aggregates (flocs) produces a continuous network throughout the suspension before settling occurs and a colloidal gel is formed. Colloidal gels may be divided into hard gels and soft gels. 1 Hard gels ...

متن کامل

Internal Dynamics and Elasticity of Fractal Colloidal Gels

The dynamic structure factor of fractal colloidal gels is shown to exhibit a stretched exponential decay to a finite plateau with an exponent of about 0.7. The value of the plateau depends on both initial particle volume fraction f0 and scattering wave vector. We show that this behavior results from the contribution of internal elastic modes of many length scales, and present a model which acco...

متن کامل

Strain Hardening of Fractal Colloidal Gels

We report on experiments on the rheology of gels formed by diffusion-limited aggregation of neutrally buoyant colloidal particles. These gels form very weak solids, with the elastic modulus, G0svd, larger than the loss modulus, G00svd, and with both G0svd and G00svd exhibiting only a very weak frequency dependence. Upon small but finite strains g , 0.45 the elastic modulus increases roughly exp...

متن کامل

Ultra-long-range dynamic correlations in a microscopic model for aging gels.

We use large-scale computer simulations to explore the nonequilibrium aging dynamics in a microscopic model for colloidal gels. We find that gelation resulting from a kinetically arrested phase separation is accompanied by "anomalous" particle dynamics revealed by superdiffusive particle motion and compressed exponential relaxation of time correlation functions. Spatiotemporal analysis of the d...

متن کامل

Length scale dependence of dynamical heterogeneity in a colloidal fractal gel

– We use time-resolved dynamic light scattering to investigate the slow dynamics of a colloidal gel. The final decay of the average intensity autocorrelation function is well described by g2(q, τ ) − 1 ∼ exp[−(τ/τf) ], with τf ∼ q −1 and p decreasing from 1.5 to 1 with increasing q. We show that the dynamics is not due to a continuous ballistic process, as proposed in previous works, but rather...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Physical review letters

دوره 84 10  شماره 

صفحات  -

تاریخ انتشار 2000